From Microcracks to Multimillion‑Dollar Fractures: The Case for Self‑Healing Polymers in Modern Engineering Applications
Self-Healing Polymers in Modern Engineering Applications
DOI:
https://doi.org/10.58445/rars.3645Keywords:
self-healing polymers, nanoparticles, hybrid, automotives, aircraft, concreteAbstract
The integration of self‑healing polymers into systems capable of autonomously repairing damage, ranges from concrete infrastructure to advanced composites used in turbine blades, aircraft wings, and other high‑performance materials such as those designed for space exploration. This application has emerged as a promising eco-friendly strategy to enhance durability, reduce maintenance, and extend longevity. These polymers are formulated as hydrogels, encapsulated healing agents, or hybrid systems incorporating nanoparticles, to seal cracks and restore mechanical integrity when activated by environmental stress such as moisture or temperature. Thus, a theoretical exploration of ‘self-healing’ materials evolved into a practical engineering toolkit that can address damage across diverse structural contexts. Emerging evidence implicates polymer chemistry, network dynamics, and environmental triggers as primary determinants of autonomous healing, supported by a growing body of studies on domestic, industrial, and aerospace materials systems. While the fundamental mechanisms governing crack sealing and moisture‑triggered swelling in many polymer systems are well established, their durability, scalability, and reliability across varied operational environments remains insufficiently understood. To address this critical knowledge gap, this article synthesizes current insights into self‑healing polymers and related hybrid systems, examines their applications from residential and community infrastructure to sophisticated industrial and aerospace environments, and highlights cost–benefit considerations that will shape their potential for widespread adoption.
References
Pezzin, Sérgio Henrique. “Mechanism of Extrinsic and Intrinsic Self-Healing in Polymer Systems.” Multifunctional Epoxy Resins, edited by Sérgio Henrique Pezzin, Springer, 2023, pp. 107–138.
Ramprasad, R., et al. “Machine Learning in Materials Informatics: Recent Applications and Prospects.” npj Computational Materials, vol. 3, 2017, p. 54.
White, Scott R., et al. “Autonomic Healing of Polymer Composites.” Nature, vol. 409, 2001, pp. 794–797.
Toohey, K. S., et al. “Self‑Healing Materials with Microvascular Networks.” Nature Materials, vol. 6, 2007, pp. 581–585.
Hager, Martin D., et al. “Self‑Healing Materials.” Advanced Materials, vol. 22, no. 47, 2010, pp. 5424–5430.
Utrera-Barrios, Saul, et al. “Evolution of Self‑Healing Elastomers, from Extrinsic to Combined Intrinsic Mechanisms: A Review.” Materials Horizons, vol. 7, no. 11, 2020, pp. 2553–2570.
Stanzione, Joseph F., et al. “Bio‑Based Polymers and Composites for Self‑Healing Materials.” ACS Sustainable Chemistry & Engineering, vol. 9, no. 3, 2021, pp. 892–910.
Urry, Dan W. “Physical Chemistry of Biological Free Energy Transduction As Demonstrated by Elastic Protein‑Based Polymers.” Journal of Physical Chemistry B, vol. 101, no. 51, 1997, pp. 11007–11028.
Li, Jinxing, and David J. Mooney. “Designing Hydrogels for Controlled Drug Delivery.” Nature Reviews Materials, vol. 1, 2016, pp. 1–17.
Kontiza, A., and I. A. Kartsonakis. “Smart Composite Materials with Self‑Healing Properties: A Review on Design and Applications.” Polymers, vol. 16, no. 15, 2024, p. 2115.
Ahirwar, D., R. Purohit, and S. Dixit. “Enhanced Durability, Self‑Healing and Crack Arrest in Hybrid Polymer Composite via Calcium Alginate Xerogels.” Journal of Bionic Engineering, vol. 22, 2025, pp. 3118–3139.
Dhamotharan, S., K. Pradeep, K. Saravana Prasanth, et al. “Progress in Self‑Healing Polymer Composites: Materials Design, Mechanisms, and Applications.” AIP Conference Proceedings, vol. 3221, 2024, p. 020031.
Kotov, Nicholas A., et al. “Biocompatible Nanocomposites with Self‑Healing Properties Based on Layer‑by‑Layer Assembly.” Advanced Materials, 2016.
Sharma, Sachin Kumar, et al. “Self‑Healing Polymer Nanocomposites: Mechanisms, Structure–Property Relationships, and Emerging Applications.” Polymers, vol. 18, no. 2, 2026, p. 276.
Pooja, S., and F. Tarannum. “Comparative Analysis of Autogenic and Autonomous Healing in Concrete.” Construction and Building Materials, vol. 310, 2025, p. 125678.
Powers, Carrie. “How Does a Self‑Healing Home Cell Membrane Work?” Polyguard Products, 9 Jan. 2024, www.polyguardproducts.com/....
Zhang, Yifan, et al. “Self‑Healing Materials: A Review.” Materials, vol. 15, no. 9, 2022, p. 3214.
Sangadji, S., E. Schlangen, and A. Milenkovic. “Porous Network Concrete: Novel Concept of Healable Concrete Structures.” Concrete Repair, Rehabilitation and Retrofitting III: Proceedings of the 3rd International Conference on Concrete Repair, Rehabilitation and Retrofitting (ICCRRR 2012), Cape Town, South Africa, 3–5 Sept. 2012, CRC Press, 2012, pp. 228–233.
Ghazy, M., A. El‑Zohairy, and J. Kim. “Self‑Healing Concrete: Mechanisms, Materials, and Environmental Impact.” Cement and Concrete Research, vol. 162, 2023, p. 106987.
Zhao, Y., and H. Li. “Smart Hydrogels for Autonomous Crack Repair in Concrete.” Materials Today Chemistry, vol. 25, 2022, p. 100987.
Snoeck, D., and N. De Belie. “Self‑Healing Cementitious Materials with Microfibers and Superabsorbent Polymers.” Cement and Concrete Research, vol. 74, 2015, pp. 59–67.
Snoeck, D., et al. “The Influence of Nano‑Silica and Superabsorbent Polymers on the Autogenous Healing of Cementitious Materials.” Materials, vol. 13, no. 2, 2020, p. 284.
Zhang, Wei, et al. “Nanomaterial‑Enhanced Polymer Gel Systems for Autonomous Self‑Healing in Cementitious Materials: A Comprehensive Review.” Journal of Materials Science, vol. 59, 2024, pp. 1–32.
Stellarix. “Self‑Healing Materials in the Automobile Industry.” Stellarix, [year], www.stellarix.com/...
O’Brien, Conor. “Automotive Sector Offers Road to Commercialization of Self‑Healing Materials.” Manufacturing.net, 24 Jan. 2025, www.manufacturing.net/...
Future Market Insights. Self‑Repairing Polymers Market. Future Market Insights, [year], www.futuremarketinsights.com/reports/self-repairing-polymers-market.
NASA. Self‑Healing Composites for Aerospace Applications. NASA Technical Reports Server, 2010.
Air Force Research Laboratory. Autonomic Healing of Polymer Composites. AFRL Materials Directorate, 2008.
Kotyk, M. W., et al. “Self‑Healing, Reconfigurable, and Recyclable Supramolecular Nanocomposites for Structural Applications.” Advanced Materials, vol. 31, no. 26, 2019, p. 1901563.
European Space Agency. Self‑Healing Materials for Space Applications. ESA Materials & Processes Division, 2015.
NASA Glenn Research Center. Self‑Healing Polymers for Spacecraft Structures. NASA GRC Technical Report, 2012.
Zhang, H., et al. “Self‑Healing Coatings for Aerospace Applications.” Progress in Organic Coatings, vol. 72, no. 3, 2011, pp. 423–428.
Office of Naval Research. Autonomic Corrosion‑Resistant Coatings. ONR Technical Report, 2014.
NASA Ames Research Center. Self‑Healing Ablative Materials for Thermal Protection Systems. NASA Ames TPS Division, 2013.
Sandia National Laboratories. Self‑Healing Polymers for High‑Temperature Aerospace Applications. Sandia Technical Report, 2017.
Kumar, A., et al. “Self‑Healing Epoxy Adhesives for Aerospace Composite Joints.” Composites Part A: Applied Science and Manufacturing, vol. 101, 2017, pp. 72–82.
Boeing (collaboration). “Healing of Epoxy Adhesive Layers Using Microencapsulated Agents.” Journal of Adhesion Science and Technology, 2012.
NASA Langley Research Center. Shape‑Memory Polymer Composites for Morphing Aerospace Structures. NASA LaRC Technical Report, 2010.
Wu, D., et al. “Self‑Healing Polymer Networks Based on Dynamic Covalent Chemistry.” Progress in Polymer Science, vol. 62, 2016, pp. 68–105.
Zhang, Y., et al. “Injectable Self‑Healing Hydrogels for Tissue Engineering.” Biomaterials, vol. 181, 2018, pp. 113–125.
Tee, Benjamin C.‑K., et al. “Self‑Healing Electronic Materials for a Smart and Sustainable Future.” Advanced Materials, vol. 24, no. 36, 2012, pp. 5390–5395.
Böstman, O., and H. Pihlajamäki. “Clinical Biocompatibility of Biodegradable Orthopaedic Implants for Internal Fixation: A Review.” Biomaterials, vol. 21, no. 24, 2000, pp. 2615–2621.
Stoppa, Matteo, and Alessandro Chiolerio. “Wearable Electronics and Smart Textiles: A Critical Review.” Sensors, vol. 14, no. 7, 2014, pp. 11957–11992.
Tao, Xiaoming. Handbook of Smart Textiles. Springer, 2015.
Wang, Zhong Lin, et al. “Self‑Powered Wearable Sensors and Systems Based on Nanogenerators.” Advanced Materials, vol. 30, no. 15, 2018, p. 1706960.
Lei, Zhen, et al. “Room‑Temperature Self‑Healing Polymer Dielectrics for Flexible Electronics.” Advanced Functional Materials, vol. 30, no. 12, 2020, p. 1907455.
Wang, Chao, et al. “Self‑Healing Dielectric Materials for Next‑Generation Electronics.” Nature Electronics, vol. 2, 2019, pp. 157–164.
White, Scott R., et al. “Autonomic Healing of Conductive Pathways in Polymer Composites.” Nature, vol. 409, 2001, pp. 794–797.
National Transportation Safety Board. Highway Accident Report: Pedestrian Bridge Collapse Over SW 8th Street, Miami, Florida, March 15, 2018. NTSB/HAR‑19/02, 2019.
National Transportation Safety Board. Collapse of the Forbes Avenue Bridge (Fern Hollow Bridge), Pittsburgh, Pennsylvania, January 28, 2022. NTSB/HAR‑24/01, 2024.
Occupational Safety and Health Administration. Inspection Report: Hard Rock Hotel Construction Site Collapse, New Orleans, Louisiana. U.S. Department of Labor, 2020.
Denver International Airport Runway Failures. Sutter, Lawrence L., et al. “Premature Concrete Deterioration at Denver International Airport: Investigation of Alkali–Silica Reaction and Freeze–Thaw Damage.” Cement and Concrete Research, vol. 31, no. 5, 2001, pp. 767–773.
Basement Failures in Colorado (Expansive Clay Soils). Nelson, John D., and Debora J. Miller. Expansive Soils: Problems and Practice in Foundation and Pavement Engineering. Wiley, 1997.
Colorado Geological Survey. Expansive Soils and Heaving Basements in the Front Range. CGS Special Publication 43, 2003.
Reichmanis, Elsa, et al. “Dynamic Polymer Networks for Advanced Functional Materials.” ACS Applied Polymer Materials, vol. 3, no. 2, 2021, pp. 123–135.
García, S. J. “Effect of Polymer Architecture on the Performance of Self‑Healing Coatings.” Progress in Organic Coatings, vol. 89, 2015, pp. 407–415.
Arruda, Ellen M., et al. “A Self‑Healing Elastomer Based on Mechanochemically Active Networks.” ACS Macro Letters, vol. 8, no. 11, 2019, pp. 1407–1412.
Van Tittelboom, Kim, and Nele De Belie. “Self‑Healing in Cementitious Materials—A Review.” Materials, vol. 6, no. 6, 2013, pp. 2182–2217.
Zhang, H., et al. “Self‑Healing Coatings for Automotive Applications.” Progress in Organic Coatings, vol. 72, no. 3, 2011, pp. 423–428.
Bekas, D., et al. “Self‑Healing Materials: A Review of Advances in Materials, Evaluation, Characterization and Monitoring Techniques.” Composites Part B: Engineering, vol. 87, 2016, pp. 92–119.
Wang, Jianyun, et al. “Self‑Healing Concrete by Biological Mineralization.” Materials, vol. 5, no. 12, 2012, pp. 2280–2294.
Qureshi, T. S., et al. “Self‑Healing of Cementitious Materials Using Natural Polysaccharide‑Based Hydrogels.” Construction and Building Materials, vol. 127, 2016, pp. 119–128.
Dry, Carolyn M. “Three Designs for the Internal Release of Sealants, Adhesives, and Waterproofing Chemicals into Concrete to Reduce Permeability.” Cement and Concrete Research, vol. 30, no. 12, 2000, pp. 1969–1977.
Kalaitzidou, Kyriaki, et al. “Sustainable Polymer Composites Reinforced with Bio‑Based and Recyclable Components.” Composites Part B, 2017
Strano, Michael S., et al. “Autonomic Materials for Infrastructure: Environmental and Durability Benefits.” Advanced Functional Materials, 2015.
Downloads
Posted
Categories
License
Copyright (c) 2026 Aditi Gopalakrishnan

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.